Controlled Release of β-CD-Encapsulated Thyme Essential Oil from Whey Protein Edible Packaging

Author:

Lanciu Dorofte Andreea1,Dima Cristian1ORCID,Ceoromila Alina2ORCID,Botezatu Andreea3ORCID,Dinica Rodica3ORCID,Bleoanca Iulia1ORCID,Borda Daniela1ORCID

Affiliation:

1. Faculty of Food Science and Engineering, Dunarea de Jos University of Galati, 800201 Galati, Romania

2. Cross-Border Faculty, Dunarea de Jos University of Galati, 111 Domneasca Str., 800201 Galati, Romania

3. Faculty of Science and Environment, Dunarea de Jos University of Galati, 800201 Galati, Romania

Abstract

Whey edible films (EFs) functionalized with essential oils have a high potential to be used on various foods due to their antimicrobial and antioxidant activities. Encapsulation is applied for a better retention of volatiles in EFs; however, the functional properties of EFs are modified. The properties of EFs containing thyme essential oil (TEO) encapsulated by co-precipitation in β-CD, developed in three formulae, with inclusion complexes (EF/IC1, EF/IC2, and EF/IC3, respectively) in 15:85, 26:74, and 35:65 mass ratios were studied. Thymol is the main volatile in the ICs with TEO/β-CD (50%–60% of the total volatiles). In comparison with EF/TEO, all three formulae with EF/ICs had better, but similar, WVPs (p > 0.05). The EF/IC2 displayed a different FTIR profile than EF/IC1 and EF/IC3, suggesting a smaller number of free functional groups. The EF/IC2 showed better transparency in comparison with EF/IC1 and EF/IC3. All EF/ICs moderately inhibited R. glutinis, with the strongest activity registered by EF/IC3 (p < 0.05), but did not inhibit G. candidum, while showing a strong antibacterial activity against B. cereus. All EF/ICs inhibited 65%–70% of the total free radicals. The EF/ICs ensured a gradual release of VOCs in food simulants, with a higher rate in 95% ethanol than in water. These results have demonstrated the properties of EF/ICs with TEO/β-CD as bioactive packaging systems for foods.

Publisher

MDPI AG

Subject

Materials Chemistry,Surfaces, Coatings and Films,Surfaces and Interfaces

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