Fluorescent “OFF–ON” Sensors for the Detection of Sn2+ Ions Based on Amine-Functionalized Rhodamine 6G

Author:

Rathinam BalamuruganORCID,Murugesan Vajjiravel,Liu Bo-TauORCID

Abstract

These structurally isomeric rhodamine 6G-based amino derivatives are designed to detect Sn2+ ions. The receptors exhibit rapid fluorescent “turn-on” responses towards Sn2+. The absorption (530 nm) and fluorescent intensity (551 nm) of the receptors increase when increasing the concentration of Sn2+. The hydrazine derivative exhibits more rapid sensitivity towards Sn2+ than the ethylene diamine derivative, indicating that the presence of an alkyl chain in the diamine decreases the sensitivity of the receptors towards Sn2+. The presence of carbonyl groups and terminal amino groups strongly influences the sensitivity of the chemosensors toward Sn2+ by a spirolactam ring-opening mechanism. The receptors exhibit 1:1 complexation with Sn2+ as evidenced by Job plot, and the corresponding limit of detection was found to be 1.62 × 10−7 M. The fluorescence images of the receptors and their complexes reveal their potential applications for imaging of Sn2+ in real/online samples.

Funder

the Ministry of Science and Technology, the Republic of China

Publisher

MDPI AG

Subject

Physical and Theoretical Chemistry,Analytical Chemistry

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