Environmentally Friendly Water-Based Electrolyte for Dye-Sensitized Solar Cells: Future Prospective and Outlook

Author:

Spadaro Donatella1ORCID,Barichello Jessica12,Citro Ilaria1,Calogero Giuseppe1ORCID

Affiliation:

1. Istituto per i Processi Chimico-Fisici del CNR, Viale Ferdinando Stagno d’Alcontres, n. 37, 98158 Messina, Italy

2. CHOSE—Centre for Hybrid and Organic Solar Energy, Department of Electronic Engineering, University of Rome “Tor Vergata”, 00133 Roma, Italy

Abstract

The use of traditional Dye-sensitized solar cells (DSSCs) is limited due to the use of toxic and non-environmentally safe solvents. In this review, water is proposed as a viable alternative to developing green chemistry and sustainable materials for DSSCs. However, water-based DSSCs (WBDSSCs) require improvement in their photovoltaic parameters. The detachment of dye molecules from the semiconductor and the poor solubility of iodine in water are the primary reasons for their low efficiency. This review analyzes the best results achieved by 100% aqueous electrolytes containing synthetic, organic, and natural dyes to identify the best conditions to overcome these limitations. Developing a suitable photoanode/electrolyte interface and finding a compromise in the choice of dye are the main research goals in the coming years. WBDSSCs can contribute significantly to producing clean energy using sustainable and environmentally friendly materials. Furthermore, here we report the state of the art of the emerging technology of underwater dye-sensitized solar cells, which are a promising technology for generating renewable energy in aquatic environments. Recent advancements in material science and device engineering have shown promising results in enhancing their efficiency and durability. Further research and development can make these devices a viable alternative for sustainable energy generation in a wide range of underwater applications.

Funder

Project NAUSICA

Publisher

MDPI AG

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