Zirconia Nanoparticles as Reinforcing Agents for Contemporary Dental Luting Cements: Physicochemical Properties and Shear Bond Strength to Monolithic Zirconia
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Published:2023-01-20
Issue:3
Volume:24
Page:2067
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ISSN:1422-0067
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Container-title:International Journal of Molecular Sciences
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language:en
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Short-container-title:IJMS
Author:
Beketova Anastasia1, Tzanakakis Emmanouil-Georgios C.1ORCID, Vouvoudi Evangelia2, Anastasiadis Konstantinos3ORCID, Rigos Athanasios E.14ORCID, Pandoleon Panagiotis1, Bikiaris Dimitrios2ORCID, Tzoutzas Ioannis G.5ORCID, Kontonasaki Eleana1ORCID
Affiliation:
1. Department of Prosthodontics, School of Dentistry, Faculty of Health Sciences, Aristotle University of Thessaloniki, 54124 Thessaloniki, Greece 2. Laboratory of Polymers Chemistry and Technology, Department of Chemistry, Faculty of Sciences, Aristotle University of Thessaloniki, 54124 Thessaloniki, Greece 3. Department of Biomaterials, School of Dentistry, National Kapodistrian University of Athens, 2 Thivon Str., Goudi, 11527 Athens, Greece 4. Department of Comprehensive Dentistry, College of Dentistry, Texas A&M University, 3000 Gaston Avenue, Dallas, TX 75226, USA 5. Department of Operative Dentistry, School of Dentistry, National Kapodistrian University of Athens, 2 Thivon Str., Goudi, 11527 Athens, Greece
Abstract
Nanofillers in resin materials can improve their mechanical and physicochemical properties. The present work investigated the effects of zirconia nanoparticles (NPs) as fillers in commercial dental luting cements. Two dual-cured self-adhesive composites and one resin modified glass ionomer (RMGI) luting cement were employed. Film thickness (FT), flexural strength (FS), water sorption (Wsp), and shear bond strength (SBS) to monolithic zirconia were evaluated according to ISO 16506:2017 and ISO 9917-2:2017, whereas polymerization progress was evaluated with FTIR. Photopolymerization resulted in double the values of DC%. The addition of 1% wt NPs does not significantly influence polymerization, however, greater amounts do not promote crosslinking. The sorption behavior and the mechanical performance of the composites were not affected, while the film thickness increased in all luting agents, within the acceptable limits. Thermocycling (TC) resulted in a deteriorating effect on all composites. The addition of NPs significantly improved the mechanical properties of the RMGI cement only, without negatively affecting the other cements. Adhesive primer increased the initial SBS significantly, however after TC, its application was only beneficial for RMGI. The MDP containing luting cement showed higher SBS compared to the RMGI and 4-META luting agents. Future commercial adhesives containing zirconia nanoparticles could provide cements with improved mechanical properties.
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Computer Science Applications,Spectroscopy,Molecular Biology,General Medicine,Catalysis
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