Abstract
Infrared spectroscopy (IR) quantitative analysis technology has shown excellent development potential in the field of oil and gas logging. However, due to the high overlap of the IR absorption peaks of alkane molecules and the offset of the absorption peaks in complex environments, the quantitative analysis of IR spectroscopy applied in the field puts forward higher requirements for modelling speed and accuracy. In this paper, a new type of fast IR spectroscopy quantitative analysis method based on adaptive step-sliding partial least squares (ASS-PLS) is designed. A sliding step control function is designed to change the position of the local PLS analysis model in the full spectrum band adaptively based on the relative change of the current root mean square error and the global minimum root-mean-square error for rapid modelling. The study in this paper reveals the influence of the position and width of the local modelling window on the performance, and how to quickly determine the optimal modelling window in an uncertain sample environment. The performance of the proposed algorithm has been compared with three typical quantitative analysis methods by experiments on an IR spectrum dataset of 400 alkane samples. The results show that this method has a fast quantitative modelling speed with high analysis accuracy and stability. It has important practical value for promoting IR spectroscopy gas-logging technology.
Funder
The National Natural Science Foundation of China
Subject
Energy (miscellaneous),Energy Engineering and Power Technology,Renewable Energy, Sustainability and the Environment,Electrical and Electronic Engineering,Control and Optimization,Engineering (miscellaneous)
Cited by
4 articles.
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