QCM-Based HCl Gas Sensors Using Spin-Coated Aminated Polystyrene Colloids

Abstract

Hydrogen chloride (HCl) gas is highly toxic to the human body. Therefore, HCl gas detection sensors should be installed at workplaces where trace HCl gas is continuously generated. Even though various polymer-based HCl-gas-sensing films have been developed, simpler and novel sensing platforms should be developed to ensure the cost effectiveness and reusability of the sensing platforms. Therefore, we present a simple strategy to fabricate reusable HCl-gas-sensing platforms using aminated polystyrene (a-PS) colloids and investigate their sensitivity, reusability, and selectivity using a quartz crystal microbalance (QCM). The reusable a-PS(1.0) colloidal sensor with a high degree of amination (DA) exhibited the highest binding capacity (102 μg/mg) based on the frequency change (Δf) during the HCl gas adsorption process. Further, its sensitivity and limit of detection (LOD) were 3.88 Hz/ppm and 5.002 ppm, respectively, at a low HCl gas concentration (<10 ppm). In addition, the sensitivity coefficient (k*) of the a-PS(1.0) colloid sensor with respect to HCHO was higher than that in the case of HF because of the lower binding affinity of the former with the a-PS(1.0) colloids. Based on these results, highly sensitive and reproducible a-PS colloids could be reused as an HCl-gas-sensing platform and used as an HCl sorbent in a gas column filter.