Affiliation:
1. Department of Chemistry University of York Heslington York YO10 5DD UK
2. Department of Chemistry The University of Manchester Oxford Road Manchester M13 9PL UK
Abstract
AbstractA one‐step method for the conversion of nitroarenes into phenols under operationally simple, transition‐metal‐free conditions is described. This denitrative functionalization protocol provides a concise and economical alternative to conventional three‐step synthetic sequences. Experimental and computational studies suggest that nitroarenes may be substituted by an electron‐catalysed radical‐nucleophilic substitution (SRN1) chain mechanism.
Subject
General Chemistry,Catalysis,Organic Chemistry
Cited by
7 articles.
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