Affiliation:
1. Institute for Inorganic Chemistry Julius-Maximilians-Universität Würzburg Am Hubland 97074 Würzburg Germany
2. Institute for Sustainable Chemistry & Catalysis with Boron Julius-Maximilians-Universität Würzburg Am Hubland 97074 Würzburg Germany
3. School of Chemistry and Forensic Science University of Kent Canterbury Park Wood Rd CT2 7NH UK
Abstract
AbstractThe reactions of a cyclic alkyl(amino)carbene (CAAC)‐stabilized beryllium radical with E2Ph2 (E=S, Se, Te) and of a beryllole with HEPh (E=S, Se) yield the corresponding beryllium phenylchalcogenides, including the first structurally authenticated beryllium selenide and telluride complexes. Calculations show that their Be−E bonds are best described by the interaction between the Be+ and E− fragments, with Coulombic forces accounting for ca. 55 % of the attraction and orbital interactions dominated by the σ component.
Funder
Deutsche Forschungsgemeinschaft
Julius-Maximilians-Universität Würzburg
Verband der Chemischen Industrie
Subject
General Chemistry,Catalysis,Organic Chemistry
Cited by
8 articles.
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