1. Book: Alkaline-Earth Metal Compounds: Oddities and Applications, Topics in Organometallic Chemistry, Ed. S. Harder, 2013, Springer-Verlag Berlin, Germany, ISBN 9783642362699; N. S. Poonia, A. V. Bajaj, Coordination chemistry of alkali and alkaline earth cations, Chem. Rev. 79 (1979) 389-445; M. Westerhausen, Synthesis, properties, and reactivity of alkaline earth metal bis[bis{trialkylsilyl}amides], Coord. Chem. Rev. 176 (1998) 157-210; K M. Fromm, Oxygen donor stabilized alkaline earth metal iodides,Chimia 57(2003) 175-178); K. M. Fromm, E. D. Gueneau, Structures of alkali and alkaline earth metal clusters with oxygen donor ligands, Polyhedron 23 (2004) 1479-1504; K. M. Fromm, E. D. Gueneau, A. Y. Robin, W. Maudez, J. Sague, R. Bergougnant, Recent advances in the chemistry of “clusters” and coordination polymers of alkali, alkaline earth metal and group 11 compounds, Z. Anorg. Allg. Chem. 631 (2005) 1725-1740; M. Westerhausen, Recent developments in the field of organic heterobimetallic compounds of the alkaline-earth metals; Dalton Trans. (2006) 4755–4768; K. M. Fromm, Recent advances in tailoring the aggregation of heavier alkaline earth metal halides, alkoxides and aryloxides from non-aqueous solvents, Dalton Trans. 43 (2006) 5103-5112; M. Westerhausen, M. Gärtner, R. Fischer, J. Langer, L. Yu, M. Reiher, Heavy Grignard reagents: Challenges and possibilities of aryl alkaline earth metal compounds, Chem. Eur. J. 13 (2007) 6292 – 6306; M. S. Hill, Alkali and alkaline earth metals, Annu. Rep. Prog. Chem., Sect. A 104 (2008) 64–80; G. Arzamendi, E. Arguinarena, I. Campo, S. Zabala, L.M. Gandia, Alkaline and alkaline-earth metals compounds as catalysts for the methanolysis of sunflower oil, Catal. Today 133–135 (2008) 305–313; K. M. Fromm, Coordination polymer networks with s-block metal ions, K. M. Fromm, Coord. Chem. Rev. 252 (2008) 856-885; S. Krieck, L. Yu, M. Reiher, M. Westerhausen, Subvalent organometallic compounds of the alkaline earth metals in low oxidation states, Eur. J. Inorg. Chem. (2010) 197–216; W. D. Buchanan, M. A. Guino-o, K. Ruhlandt-Senge, Highly volatile alkaline earth metal fluoroalkoxides, Inorg. Chem. 49 (2010) 7144–7155; W. D. Buchanan, D. G. Allis, K. Ruhlandt-Senge, Synthesis and stabilization—advances in organoalkaline earth metal chemistry, Chem. Commun. 46 (2010) 4449–4465; F. Gschwind, A. Crochet. W. Maudez, K. M. Fromm, From alkaline earth ion aggregates via transition metal coordination polymer networks towards heterometallic single source precursors for oxidic materials, Chimia 64 (2010) 299-302; A. Torvisco, K. Ruhlandt-Senge, s-Block Organometallics: Analysis of ion-association and noncovalent interactions on structure and function in benzyl-based compounds, Inorg. Chem. 50 (2011) 12223–12240; A. Torvisco, A. Y. O’Brian, K. Ruhlandt-Senge, Advances in alkaline earth-nitrogen chemistry, Coord. Chem. Rev. 255 (2011) 1268–1292. M. S. Hill, D. J. Liptrot, C. Weetman, Alkaline earths as main group reagents in molecular catalysis, Chem. Soc. Rev. 45 (2016) 972-988; H. Bauer, K. Thum, M. Alonso, C. Fischer, S. Harder, Alkene transfer hydrogenation with alkaline-earth metal catalysts, Angew. Chem. Int. Ed. 58 (2019) 4248–4253; M. S. Gyngazova, L. Grazia, A. Lolli, G. Innocenti, T. Tabanelli, M. Mella, S. Albonetti, F. Cavani, J. Catal. 372 (2019) 61-73.
2. Beryllium chemistry the safe way: a theoretical evaluation of low oxidation state beryllium compounds;Couchman;Dalton Trans.,2013
3. Neutral zero-valent s-block complexes with strong multiple bonding;Arrowsmith;Nat. Chem.,2016
4. The crystal and molecular structure of beryllium hydride;Smith;Solid State Comm.,1988
5. The crystal structure of aluminum hydride;Turley;Inorg. Chem.,1969