Bis(difluoromethyl)trimethylsilicate Anion: A Key Intermediate in Nucleophilic Difluoromethylation of Enolizable Ketones with Me3 SiCF2 H-Reference-Cited by-同舟云学术

Bis(difluoromethyl)trimethylsilicate Anion: A Key Intermediate in Nucleophilic Difluoromethylation of Enolizable Ketones with Me3 SiCF2 H

Published:2016-08-24 Issue:41 Volume:55 Page:12632-12636
ISSN:1433-7851
Container-title:Angewandte Chemie International Edition
language:en
Short-container-title:Angew. Chem. Int. Ed.

Author:

Chen Dingben¹²,Ni Chuanfa¹,Zhao Yanchuan¹,Cai Xian¹,Li Xinjin¹,Xiao Pan¹,Hu Jinbo¹

Affiliation:

1. Key Laboratory of Organofluorine Chemistry; Shanghai Institute of Organic Chemistry; Chinese Academy of Sciences; 345 Ling-Ling Road Shanghai 200032 China

2. College of Pharmaceutical and Chemical Engineering; Taizhou University; Taizhou, Zhejiang 318000 China

Funder

National Basic Research Program of China

National Natural Science Foundation of China

Shanghai Science and Technology program

Youth Innovation Promotion Association CAS

Chinese Academy of Sciences

Publisher

Wiley

Subject

General Chemistry,Catalysis

Reference71 articles.

1. Reactivity of penta- and hexacoordinate silicon compounds and their role as reaction intermediates

2. Comparison of Phosphorus and Silicon: Hypervalency, Stereochemistry, and Reactivity

3. Five- and six-membered silicon–carbon heterocycles. Part 2. Synthetic modifications and applications of silacycles

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