<scp>Graphene‐Oxide</scp> Mediated Chemodivergent <scp>Ring‐Opening</scp> of Cyclobutanols-Reference-Cited by-同舟云学术

Graphene‐Oxide Mediated Chemodivergent Ring‐Opening of Cyclobutanols

Published:2023-03-28 Issue:11 Volume:41 Page:1333-1340
ISSN:1001-604X
Container-title:Chinese Journal of Chemistry
language:en
Short-container-title:Chin. J. Chem.

Author:

Brunetti Andrea¹,Pintus Angela²,Lombardi Lorenzo¹,Kovtun Alessandro²,Mascietti Federico¹,Bruno Francesco³,Ravera Enrico³,Melucci Manuela²,Bertuzzi Giulio¹⁴,Bandini Marco¹⁴

Affiliation:

1. Dipartimento di Chimica “Giacomo Ciamician”, Alma Mater Studiorum Università di Bologna Via Selmi 2, 40126 Bologna Italy

2. Istituto per la Sintesi e la Fotoreattività (ISOF) – CNR Via Gobetti, 101, 40129 Bologna Italy

3. Magnetic Resonance Center (CERM) University of Florence, Via L. Sacconi 6, 50019 Sesto Fiorentino, Italy; Department of Chemistry “Ugo Schiff”, University of Florence Via della Lastruccia 3 50019 Sesto Fiorentino Italy

4. Center for Chemical Catalysis – C3, Alma Mater Studiorum Università di Bologna via Selmi 2, 40126 Bologna Italy

Abstract

Comprehensive SummaryThe chemodivergent ring‐opening of cyclobutanols is described under the carbocatalytic assistance of graphene oxide (GO). The protocol enables the synthesis of diversely functionalized dienes or indenes (26 examples) based on the amount of GO employed. Spectroscopic (XPS and ssNMR) as well as experimental investigations revealed a direct involvement of the π‐domains of GO in tuning the stability of carbocationic intermediates during the reaction.

Publisher

Wiley

Subject

General Chemistry

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/cjoc.202200757

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