Synthesis of Indenes via Graphene Oxide Mediated Manipulation of Morita‐Baylis‐Hillman Alcohols-Reference-Cited by-同舟云学术

Synthesis of Indenes via Graphene Oxide Mediated Manipulation of Morita‐Baylis‐Hillman Alcohols

Published:2023-09-06 Issue:37 Volume:26 Page:
ISSN:1434-193X
Container-title:European Journal of Organic Chemistry
language:en
Short-container-title:Eur J Org Chem

Author:

Mantovani Sebastiano¹,Pintus Angela¹,Kovtun Alessandro¹,Bertuzzi Giulio²³,Melucci Manuela¹,Bandini Marco²³^ORCID

Affiliation:

1. Istituto per la Sintesi Organica e Fotoreattività (ISOF) – CNR Via Gobetti 101 40129 Bologna Italy

2. Dipartimento di Chimica “Giacomo Ciamician” Alma Mater Studiorum – Università di Bologna Via P. Gobetti 85 40129 Bologna Italy

3. Center for Chemical Catalysis – C³ Via P. Gobetti 85 40129 Bologna Italy

Abstract

AbstractA new metal‐free synthetic approach to functionalized indenes is documented. The use of commercially available graphene oxide (GO) allowed the direct access to indenyl cores (yield up to 80 %) via intramolecular Friedel‐Crafts‐type allylic alkylations with readily available Morita‐Baylis‐Hillman alcohols. Combined experimental and spectroscopic investigations contributed to shed light on the reaction mechanism dealing with a nanostructured carbon material‐based C−C bond forming reaction.

Funder

Università di Bologna

Ministero dell’Istruzione, dell’Università e della Ricerca

Publisher

Wiley

Subject

Organic Chemistry,Physical and Theoretical Chemistry

Reference80 articles.

1. For a representative collection of studies see:

2. Enrasentan, an Antagonist of Endothelin Receptors

3. Three Novel 5(6.RAR.7)Abeoabietane-Type Diterpenes from the Bark of Taiwania cryptomerioides

4. Total Synthesis of Taiwaniadducts B, C, and D

5. Biomimetic Total Synthesis of Cyanosporaside Aglycons from a Single Enediyne Precursor through Site-Selectivep-Benzyne Hydrochlorination

Cited by 2 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Graphene Oxide‐Arginine Composites: Efficient Dual Function Materials for Integrated CO₂ Capture and Conversion;ChemSusChem;2024-01-29

2. cis-Selective [5＋2]-Cycloaddition Reactions of Cyclic Morita-Baylis- Hillman Alcohols and Its Analogues with Arylethylenes Catalyzed by Ag(I);Chinese Journal of Organic Chemistry;2024