A Comprehensive Review of Organic Hole‐Transporting Materials for Highly Efficient and Stable Inverted Perovskite Solar Cells

Author:

Duan Yuwei1,Chen Yu1,Wu Yihui2,Liu Zhike3,Liu Shengzhong3,Peng Qiang12ORCID

Affiliation:

1. College of Materials and Chemistry & Chemical Engineering Chengdu University of Technology Chengdu 610059 P. R. China

2. School of Chemical Engineering Key Laboratory of Green Chemistry and Technology of Ministry of Education and State Key Laboratory of Polymer Materials Engineering Sichuan University Chengdu 610065 P. R. China

3. Key Laboratory of Applied Surface and Colloid Chemistry Ministry of Education Shaanxi Key Laboratory for Advanced Energy Devices Shaanxi Engineering Lab for Advanced Energy Technology School of Materials Science and Engineering Shaanxi Normal University Xi'an 710119 P. R. China

Abstract

AbstractInverted perovskite solar cells (IPSCs) have attracted unprecedented attention due to their negligible hysteresis, long‐term operational stability, low temperature, and cost‐effective fabrication process, as well as wide applications. The power conversion efficiency (PCE) of IPSCs has skyrocketed from 3.9% in 2013 to certified 26.1% in 2023, which is over the certified 25.8% of regular counterpart, benefiting from the emergence of a great number of organic hole‐transporting materials (HTM). This review provides an overview of the recent development of organic hole‐transporting materials in the efficiency and stability of IPSCs, including organic small molecules and conjugated conductive polymers. The effective strategies for the charge‐transport layer and perovskite films of IPSCs are also discussed. Finally, the prospective for further development of IPSCs is outlined, including developing novel hole‐transporting materials and fabricating techniques to meet the requirements of commercial application.

Funder

National Natural Science Foundation of China

Publisher

Wiley

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