Variable Borohydride Hapticity in Nickel(II) Scorpionate Complexes [(TpR,Me)Ni(ηn‐BH4)]: TpR,Me = hydrotris{3‐R‐5‐methyl‐1‐pyrazolyl}borate; R = Ph, n = 3 vs. R = Me, n = 4
Author:
Affiliation:
1. Department of Chemistry and Biochemistry Ohio University 45701 Athens Ohio USA
2. C. Eugene Bennett Department of Chemistry West Virginia University 26506 Morgantown West Virginia USA
Publisher
Wiley
Subject
Inorganic Chemistry
Link
https://onlinelibrary.wiley.com/doi/pdf/10.1002/ejic.201501330
Reference86 articles.
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3. Synthesis, Structure, and Reactivity of Co(II) and Ni(II) PCP Pincer Borohydride Complexes
4. Reactions of the tripod ligand tris(2-diphenylphosphinoethyl)phosphine with cobalt(II) and nickel(II) salts and sodium borohydride. Structural characterization of a five-coordinate cobalt(I) hydride complex
5. Room-Temperature Synthesis of Nickel Borides via Decomposition of NaBH4 Promoted by Nickel Bromide
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1. Conformational polymorphs of the homoleptic scorpionate sandwich complex [(TpPh,Me)2Ni], TpPh,Me=hydrotris(3-phenyl-5-methylpyrazol-1-yl)borate: Ligand substituent effects include intramolecular non-covalent interactions;Journal of Organometallic Chemistry;2024-04
2. Mechanochemical Synthesis and Reactivity of a Stable Nickel Borohydride;Helvetica Chimica Acta;2023-04-25
3. Synthesis, structural properties and reactivity of ruthenocene-based pincer Pd(ii) tetrahydroborate;Dalton Transactions;2019
4. Mono- and dinuclear Ni(i) products formed upon bromide abstraction from the Ni(i) ring-expanded NHC complex [Ni(6-Mes)(PPh3)Br];Dalton Transactions;2018
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