Synthesis, structural properties and reactivity of ruthenocene-based pincer Pd(ii) tetrahydroborate-Reference-Cited by-同舟云学术

Synthesis, structural properties and reactivity of ruthenocene-based pincer Pd(ii) tetrahydroborate

Published:2019 Issue:33 Volume:48 Page:12720-12729
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Safronov Sergey V.¹²³⁴,Gutsul Evgenii I.¹²³⁴,Golub Igor E.¹²³⁴^ORCID,Dolgushin Fedor M.¹²³⁴,Nelubina Yulia V.¹²³⁴,Filippov Oleg A.¹²³⁴^ORCID,Epstein Lina M.¹²³⁴,Peregudov Alexander S.¹²³⁴,Belkova Natalia V.¹²³⁴^ORCID,Shubina Elena S.¹²³⁴⁵^ORCID

Affiliation:

1. A. N. Nesmeyanov Institute of Organoelement Compounds

2. Russian Academy of Sciences (INEOS RAS)

3. 119991 Moscow

4. Russia

5. Peoples’ Friendship University of Russia (RUDN University)

Abstract

Non-covalent interactions determine the structure, crystal packing and reactivity of isolated ruthenocene-based pincer Pd(ii) complexes. Bifurcate dihydrogen-bonded complexes are active intermediates of tetrahydroborate alcoholysis.

Funder

Russian Foundation for Basic Research

Ministry of Education and Science of the Russian Federation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT02176K

Reference93 articles.

1. The Heck Reaction as a Sharpening Stone of Palladium Catalysis

2. The Asymmetric Intramolecular Heck Reaction in Natural Product Total Synthesis