Phosphaalkenes R 1 C(O)–P=C(NMe 2 ) 2 (R 1 =Ph, 4‐EtC 6 H 4 ): Versatile Reagents for 1,3‐Dipolar Cycloadditions to Phosphenium Complexes [Cp(CO) 2 M = PPh 2 ] (M = Mo, W)
Author:
Affiliation:
1. Fakultät für Chemie der Universität Bielefeld Universitätsstrasse 25, 33615 Bielefeld, Germany, Fax: +49‐521‐106‐6146
Publisher
Wiley
Subject
Inorganic Chemistry
Link
https://onlinelibrary.wiley.com/doi/pdf/10.1002/ejic.200700440
Reference18 articles.
1. Phosphaalkenes with Inverse Electron Density
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3. Reactivity of the Inversely Polarized Phosphaalkenes RP=C(NMe2)2 (R=tBu, Me3Si, H) towards Arylcarbene Complexes [(CO)5M=C(OEt)Ar] (Ar=Ph, M=Cr, W; Ar=2-MeC6H4, 2-MeOC6H4, M=W)
4. Reactivity of the Inversely Polarized Phosphaalkene HPC(NMe2)2 Toward Carbene Tungsten Complexes [(CO)5WC(R1)OR2] (R1 = c-C3H5, c-C5H9; R2 = Me, Et, Me3Si): A Novel Access to η1-Phosphaalkene Complexes [(CO)5W−P(R2)C(H)NMe2]
5. Synthesis and Structure of the First η 3 ‐1,2‐Diphosphaallyl Complexes [(η 5 ‐C 5 H 5 )(CO) 2 M{η 3 ‐RPPC(SiMe 3 ) 2 }] (M = Mo, R = t Bu, Cy; M = W, R = t Bu) from [(η 5 ‐C 5 H 5 )(CO) 2 M=P=C(SiMe 3 ) 2 ] (M = Mo, W) and Inversely Polarized Phosphaalkenes RP=C(NMe 2 ) 2 (R = t Bu, Cy)
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