Reactivity of the Inversely Polarized Phosphaalkene HPC(NMe2)2 Toward Carbene Tungsten Complexes [(CO)5WC(R1)OR2] (R1 = c-C3H5, c-C5H9; R2 = Me, Et, Me3Si): A Novel Access to η1-Phosphaalkene Complexes [(CO)5W−P(R2)C(H)NMe2]
Author:
Affiliation:
1. Fakultät für Chemie der Universität Bielefeld, Universitätsstrasse 25, D-33615 Bielefeld, Germany
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om030578s
Reference13 articles.
1. Reactivity of the Metallophosphaalkene [(η5-C5Me5)(CO)2FeP=C(NMe2)2] towards Alkyl-, Aryl-, Alkenyl-, and Alkynylcarbene Complexes [(CO)5M=C(OEt)R] (M=Cr, W; R=CH3, Ph, CH=CHPh, C≡CPh)
2. Reactivity of the Inversely Polarized Phosphaalkenes RP=C(NMe2)2 (R=tBu, Me3Si, H) towards Arylcarbene Complexes [(CO)5M=C(OEt)Ar] (Ar=Ph, M=Cr, W; Ar=2-MeC6H4, 2-MeOC6H4, M=W)
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