Synthesis and Structure of the First η 3 ‐1,2‐Diphosphaallyl Complexes [(η 5 ‐C 5 H 5 )(CO) 2 M{η 3 ‐RPPC(SiMe 3 ) 2 }] (M = Mo, R = t Bu, Cy; M = W, R = t Bu) from [(η 5 ‐C 5 H 5 )(CO) 2 M=P=C(SiMe 3 ) 2 ] (M = Mo, W) and Inversely Polarized Phosphaalkenes RP=C(NMe 2 ) 2 (R = t Bu, Cy)-Reference-Cited by-同舟云学术

Synthesis and Structure of the First η 3 ‐1,2‐Diphosphaallyl Complexes [(η 5 ‐C 5 H 5 )(CO) 2 M{η 3 ‐RPPC(SiMe 3 ) 2 }] (M = Mo, R = t Bu, Cy; M = W, R = t Bu) from [(η 5 ‐C 5 H 5 )(CO) 2 M=P=C(SiMe 3 ) 2 ] (M = Mo, W) and Inversely Polarized Phosphaalkenes RP=C(NMe 2 ) 2 (R = t Bu, Cy)

Published:2005-05 Issue:10 Volume:2005 Page:1940-1946
ISSN:1434-1948
Container-title:European Journal of Inorganic Chemistry
language:en
Short-container-title:Eur. J. Inorg. Chem.

Author:

Weber Lothar¹,Noveski Gabriel¹,Lassahn Ulrich¹,Stammler Hans‐Georg¹,Neumann Beate¹

Affiliation:

1. Fakultät für Chemie der Universität Bielefeld Universitätsstrasse 25, 33615 Bielefeld, Germany, Fax: +49‐521‐106‐6146

Publisher

Wiley

Subject

Inorganic Chemistry

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/ejic.200400995

Reference28 articles.

1. Phosphaalkenes with Inverse Electron Density

2. Reaction of metal-carbene complexes with Wittig reagents. New vinyl ether synthesis

4. Reactivity of the Metallophosphaalkene [(η5-C5Me5)(CO)2FeP=C(NMe2)2] towards Alkyl-, Aryl-, Alkenyl-, and Alkynylcarbene Complexes [(CO)5M=C(OEt)R] (M=Cr, W; R=CH3, Ph, CH=CHPh, C≡CPh)

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