Synthese, Struktur und Reaktivität von η3-1,2-Diphosphaallylkomplexen sowie von [{(η5-C5H5)(CO)2W–Co(CO)3}{μ-AsCH(SiMe3)2}(μ-CO)]
Author:
Publisher
Wiley
Subject
Inorganic Chemistry
Reference27 articles.
1. Synthesis and Structure of the First η 3 ‐1,2‐Diphosphaallyl Complexes [(η 5 ‐C 5 H 5 )(CO) 2 M{η 3 ‐RPPC(SiMe 3 ) 2 }] (M = Mo, R = t Bu, Cy; M = W, R = t Bu) from [(η 5 ‐C 5 H 5 )(CO) 2 M=P=C(SiMe 3 ) 2 ] (M = Mo, W) and Inversely Polarized Phosphaalkenes RP=C(NMe 2 ) 2 (R = t Bu, Cy)
2. Syntheses and molecular structures of η3-[(η5-Cp*)(CO)2Fe–AsPC(SiMe3)2]M(CO)2(η5-Cp) (M = Mo, W): the first complexes featuring η3-arsaphosphaallyl ligands
3. Reactivity of the Inversely Polarized Arsaalkenes R–As=C(NMe 2 ) 2 {R = [(η 5 ‐C 5 Me 5 )(CO) 2 Fe], t BuC(O), 4‐Et–C 6 H 4 C(O)} towards Phosphavinylidene Complexes [η 5 ‐(C 5 H 5 )(CO) 2 M=P=C(SiMe 3 ) 2 ] (M = Mo, W)
4. Reactivity of the Inversely Polarised Arsaalkenes R–As=C(NMe 2 ) 2 {R = [(η 5 ‐C 5 Me 5 )(CO) 2 Fe], t BuC(O)} Towards Vinylidene Complexes [η 5 ‐(C 5 H 5 )(CO)(NO)W=C=C(H)R] (R = Ph, t Bu)
5. Arsaalkenes R−AsC(NMe2)2 [R = PhC(O), 4-EtC6H4C(O), 2,4,6-Me3C6H2C(O), tBuC(O), Me3Si]: Versatile Reagents in the Chemistry of Heterocumulenes
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2. Expedient Synthesis of a Metallostibine Os 2 (CO) 8 (µ‐SbPh): An Unusual and Strong Two‐Electron‐Donor Ligand;European Journal of Inorganic Chemistry;2017-05-18
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