Lithium‐Ion Battery Cathode Recycling through a Closed‐Loop Process Using a Choline Chloride‐Ethylene Glycol‐Based Deep‐Eutectic Solvent in the Presence of Acid

Abstract

AbstractThis study evaluates the ability of a choline chloride:ethylene glycol‐based deep eutectic solvent (DES) to dissolve lithium cobalt oxide (LCO) which is used as a cathode active material in Li‐ion batteries. Both a commercial powder and spent cathodes have been used. It was demonstrated that if HCl is added in a small proportion, a rapid and efficient LCO dissolution can be achieved. Indeed, if more than three protons are added per one cobalt atom present in the LCO structure, a complete dissolution of the material is accomplished within 2 h at 80 °C. This result might be considered as a viable alternative compared to the literature where much longer reaction times and higher temperatures are applied to achieve similar results with the same DES system used either pure or in presence of additional reducing agents. It was further demonstrated that Co and Li can be fully precipitated after Li2CO3 addition. This precipitation does neither pollute the DES nor leads to its degradation provided the pH does not exceed 10. Finally, it was shown that two additional reuse cycles can be carried out without any decrease of recovery efficiency, while no degradation products have been detected within the DES phase.