Fast Photoresponse from Hybrid Monolayer MoS2/Organic Photodetector

Author:

Raoufi Meysam1,Rühl Steffen2,Chandrabose Sreelakshmi1,Shukla Atul1,Sun Bowen1,Kratochvil Emil-List23,Blumstengel Sylke2,Neher Dieter1ORCID

Affiliation:

1. Institute of Physics and Astronomy University of Potsdam 14476 Potsdam Germany

2. Institut für Chemie Institut für Physik and IRIS Adlershof Humboldt-Universität zu Berlin Zum Großen Windkanal 2 12489 Berlin Germany

3. Helmholtz-Zentrum Berlin für Materialien und Energie Hahn-Meitner-Platz 1 14109 Berlin Germany

Abstract

As a direct‐bandgap transition semiconductor with high carrier mobility, monolayer (ML) transition metal dichalcogenides (TMDCs) have attracted significant attention as a promising class of material for photodetection. It is reported that these layers exhibit a persistent photoconductance (PPC) effect, which is assigned to long‐lasting hole capture by deep traps. Therefore, TMDCs‐based photodetectors show a high photoresponse but also a slow response. Herein, intensity‐modulated photocurrent spectroscopy (IMPS) with steady‐state background illumination is performed to investigate the photoresponse dynamics in a hybrid photodetector based on ML MoS2 covered with an ultrathin layer of phthalocyanine (H2Pc) molecules. The results demonstrate that adding the H2Pc layer speeds up the photoresponse of the neat ML‐MoS2 photodetector by almost two orders of magnitude without deteriorating its responsivity. The origin of these improvements is revealed by applying the Hornbeck–Haynes model to the photocarrier dynamics in the IMPS experiment. It is shown that the improved response speed of the hybrid device arises mostly from a faster detrapping of holes in the presence of the H2Pc layer, while the trap densities remain rather unchanged. Meanwhile, the additional absorption of photons in the H2Pc layer contributes to photocarrier generation, resulting in an enlarged responsivity of the hybrid device.

Publisher

Wiley

Subject

Materials Chemistry,Electrical and Electronic Engineering,Surfaces, Coatings and Films,Surfaces and Interfaces,Condensed Matter Physics,Electronic, Optical and Magnetic Materials

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