Regio‐ and Enantioselective Synthesis of Trifluoromethyl‐Substituted Homoallylic α‐Tertiary NH 2 ‐Amines by Reactions Facilitated by a Threonine‐Based Boron‐Containing Catalyst
Author:
Affiliation:
1. Department of Chemistry Merkert Chemistry Center Boston College Chestnut Hill MA 02467 USA
2. Supramolecular Science and Engineering Institute University of Strasbourg CNRS 67000 Strasbourg France
Funder
National Institute of General Medical Sciences
Publisher
Wiley
Subject
General Chemistry,Catalysis
Link
https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.202001184
Reference77 articles.
1. For relevant reviews see:
2. Asymmetric catalysis for the construction of quaternary carbon centres: nucleophilic addition on ketones and ketimines
3. Asymmetric Synthesis of Tertiary Alcohols and α-Tertiary Amines via Cu-Catalyzed C−C Bond Formation to Ketones and Ketimines
4. Catalytic Enantioselective Formation of C−C Bonds by Addition to Imines and Hydrazones: A Ten-Year Update
5. Quaternary centres bearing nitrogen (α-tertiary amines) as products of molecular rearrangements
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