Regio‐ and Enantioselective Synthesis of Trifluoromethyl‐Substituted Homoallylic α‐Tertiary NH 2 ‐Amines by Reactions Facilitated by a Threonine‐Based Boron‐Containing Catalyst-Reference-Cited by-同舟云学术

Regio‐ and Enantioselective Synthesis of Trifluoromethyl‐Substituted Homoallylic α‐Tertiary NH 2 ‐Amines by Reactions Facilitated by a Threonine‐Based Boron‐Containing Catalyst

Published:2020-05-08 Issue:28 Volume:59 Page:11448-11455
ISSN:1433-7851
Container-title:Angewandte Chemie International Edition
language:en
Short-container-title:Angew. Chem. Int. Ed.

Author:

Fager Diana C.¹,Morrison Ryan J.¹,Hoveyda Amir H.¹²^ORCID

Affiliation:

1. Department of Chemistry Merkert Chemistry Center Boston College Chestnut Hill MA 02467 USA

2. Supramolecular Science and Engineering Institute University of Strasbourg CNRS 67000 Strasbourg France

Funder

National Institute of General Medical Sciences

Publisher

Wiley

Subject

General Chemistry,Catalysis

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.202001184

Reference77 articles.

1. For relevant reviews see:

2. Asymmetric catalysis for the construction of quaternary carbon centres: nucleophilic addition on ketones and ketimines

3. Asymmetric Synthesis of Tertiary Alcohols and α-Tertiary Amines via Cu-Catalyzed C−C Bond Formation to Ketones and Ketimines

4. Catalytic Enantioselective Formation of C−C Bonds by Addition to Imines and Hydrazones: A Ten-Year Update

5. Quaternary centres bearing nitrogen (α-tertiary amines) as products of molecular rearrangements

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