Asymmetric Synthesis of Tertiary Alcohols and α-Tertiary Amines via Cu-Catalyzed C−C Bond Formation to Ketones and Ketimines
Author:
Affiliation:
1. Graduate School of Pharmaceutical Sciences, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-0033, Japan
Publisher
American Chemical Society (ACS)
Subject
General Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/cr078340r
Reference216 articles.
1. The Sharpless asymmetric dihydroxylation of trisubstituted olefins can produce enantiomerically-enriched tertiary alcohols. For review, see:Johnson, R. A. and Sharpless, K. B.InCatalytic Asymmetric Synthesis;Ojima, I., Ed.Wiley-VCH:New York, 2000; pp357−398.
2. Lewis Acid-Catalyzed Enantioselective Hydroxylation Reactions of Oxindoles and β-Keto Esters Using DBFOX Ligand
3. Asymmetric Catalysis Special Feature Part II: Expanding the scope of asymmetric electrophilic atom-transfer reactions: Titanium- and ruthenium-catalyzed hydroxylation of -ketoesters
4. Axially Chiral Guanidine as Highly Active and Enantioselective Catalyst for Electrophilic Amination of Unsymmetrically Substituted 1,3-Dicarbonyl Compounds
5. Asymmetric Construction of Quaternary Stereocenters by Direct Organocatalytic Amination of α-Substituted α-Cyanoacetates and β-Dicarbonyl Compounds
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