Affiliation:
1. Institute of Stable Isotopes, State Committee on the Uses of Atomic Energy, Tbilisi 380086, Georgia
Abstract
CF3COF dissociation channels in the pressure region from 0.2 to 4 Torr under the pulsed CO2 laser radiation are investigated. The dissociation products COF2, C2F6, and CF4 are identified according to the infrared spectra, and their relative output is measured over the whole range of the initial substance pressures. A scheme of laserochemical reactions describing the trifluoroacetyl fluoride dissociation channels is presented. The correctness of the chosen scheme is confirmed on the basis of the elementary theory of active collisions. The measurements of CF3COF dissociation selectivity for 18O and 13C are given.
Subject
Spectroscopy,Biochemistry,Atomic and Molecular Physics, and Optics
Cited by
10 articles.
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