Monohydride complexes of W (IV) containing bulky selenolate ligands: X-ray crystal structure determination of [WH(SeC6H3Pri2-2,6)3(PMe2Ph)2]
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Publisher
Elsevier BV
Subject
Materials Chemistry,Inorganic Chemistry,Physical and Theoretical Chemistry
Reference37 articles.
1. Monohydride complexes of molybdenum(IV) and tungsten(IV) containing bulky thiolate ligands: X-ray crystal structures of [MH(SC6H2Pr I 3-2,4,6)3(PMe2Ph)2], M = Mo or W
2. Reactions of the hydridethiolate complexes [MH(SC6H2R3-2,4,6)3(PMe2Ph)2](M = Mo or W, R = Me or Pri): X-ray crystal structures of [M(SC6H2Pri 3-2,4,6)2(CO)2(PMe2Ph)2](M = Mo or W)
3. Elucidation of the structures of the hydridothiolato complexes WH(SC6H2Pri3-2,4,6)3(L)(PMe2Ph), L = PMe2Ph or pyridine, by NMR and X-ray techniques
4. Cleavage of an aryl carbon–sulfur bond in hydride–thiolate complexes of molybdenum and tungsten. Crystal structures of [{Mo(SC6H2Pri3-2,4,6)(OMe)(PMePh2)}2(µ-S)2] and [{Mo(SC6H2Pri3-2,4,6)(OEt)(PEtPh2)}2(µ-S)2]
5. Five-co-ordinate complexes [MoH(SC6H2R3-2,4,6)3(PR′Ph2)](R = Me or Pri, R′= Me or Et) and their reactions with nitrogen donors. Crystal structures of [MoH(SC6H2Pri3-2,4,6)3(C5H5N)(PMe2Ph)], [MoH(NC5H4S-2)2(SC6H2Pri3-2,4,6)(PEtPh2)] and [PPh4][MoO(SC6H2Pri3-2,4,6)4]
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