Lewis Bases Trigger Intramolecular CH–Bond Activation: ( t Bu 3 SiO) 2 W=N t Bu [rlhar2] ( t Bu 3 SiO)(κ O ,κ C ‐ t Bu 2 SiOCMe 2 CH 2 )HW=N t Bu-Reference-Cited by-同舟云学术

Lewis Bases Trigger Intramolecular CH–Bond Activation: ( t Bu 3 SiO) 2 W=N t Bu [rlhar2] ( t Bu 3 SiO)(κ O ,κ C ‐ t Bu 2 SiOCMe 2 CH 2 )HW=N t Bu

Published:2013-05-10 Issue:22-23 Volume:2013 Page:4056-4067
ISSN:1434-1948
Container-title:European Journal of Inorganic Chemistry
language:en
Short-container-title:Eur. J. Inorg. Chem.

Author:

Marshak Michael P.¹,Rosenfeld Devon C.¹,Morris Wesley D.¹,Wolczanski Peter T.¹,Lobkovsky Emil B.¹,Cundari Thomas R.²

Affiliation:

1. Department of Chemistry & Chemical Biology, Baker Laboratory, Cornell University, Ithaca, New York 14853, USA, http://chemistry.cornell.edu/faculty/detail.cfm?netid=ptw2

2. Department of Chemistry, University of North Texas, Box 305070, Denton, Texas 76203‐5070, USA

Publisher

Wiley

Subject

Inorganic Chemistry

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/ejic.201300234

Reference71 articles.

1. The Reductive Elimination of Methane from ansa ‐Hydrido(methyl)metallocenes of Molybdenum and Tungsten: Application of Hammond’s Postulate to Two‐State Reactions

2. Orbital Splitting and Pairing Energy in Open‐Shell Organometallics: A Study of Two Families of 16‐Electron Complexes [Cp 2 M] (M = Cr, Mo, W) and [CpM(PH 3 )] (M = Co, Rh, Ir)

3. A Two-State Computational Investigation of Methane CH and Ethane CC Oxidative Addition to [CpM(PH3)]n+ (M=Co, Rh, Ir;n=0, 1)

4. A Computational Study of Ethylene C−H Bond Activation by [Cp*Ir(PR3)]

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