Orbital Splitting and Pairing Energy in Open‐Shell Organometallics: A Study of Two Families of 16‐Electron Complexes [Cp 2 M] (M = Cr, Mo, W) and [CpM(PH 3 )] (M = Co, Rh, Ir)-Reference-Cited by-同舟云学术

Orbital Splitting and Pairing Energy in Open‐Shell Organometallics: A Study of Two Families of 16‐Electron Complexes [Cp 2 M] (M = Cr, Mo, W) and [CpM(PH 3 )] (M = Co, Rh, Ir)

Published:2005-06 Issue:12 Volume:2005 Page:2324-2331
ISSN:1434-1948
Container-title:European Journal of Inorganic Chemistry
language:en
Short-container-title:Eur. J. Inorg. Chem.

Author:

Poli Rinaldo¹,Cacelli Ivo²

Affiliation:

1. Laboratoire de Chimie de Coordination, UPR CNRS 8241, 205 Route de Narbonne, 31077 Toulouse Cedex, France, Fax: +33‐561‐553‐003

2. Dipartimento di Chimica e Chimica Industriale, Università di Pisa, Via Risorgimento 35, 56126 Pisa, Italy

Publisher

Wiley

Subject

Inorganic Chemistry

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/ejic.200400839

Reference44 articles.

1. Open-Shell Organometallics as a Bridge between Werner-Type and Low-Valent Organometallic Complexes. The Effect of the Spin State on the Stability, Reactivity, and Structure

2. Open shell organometallics: a general analysis of their electronic structure and reactivity

3. Two-State Reactivity in Organometallic Gas-Phase Ion Chemistry

4. Two-State Reactivity as a New Concept in Organometallic Chemistry

5. On the spin-forbiddeness of gas-phase ion–molecule reactions: a fruitful intersection of experimental and computational studies

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