Affiliation:
1. School of Chemical Sciences, University of Chinese Academy of Sciences, Beijing 100049, China
Abstract
The enantioconvergent alkyl–alkyl coupling involves two competitive catalytic cycles with nickel(0) and nickel(i) active catalysts, respectively. K3PO4 plays a crucial role to enable the hydride transfer from hydrosilane to nickel–bromine species.
Funder
National Natural Science Foundation of China
Fundamental Research Funds for the Central Universities
University of Chinese Academy of Sciences
Publisher
Royal Society of Chemistry (RSC)
Reference109 articles.
1. Comprehensive Asymmetric Catalysis , ed. E. N. Jacobsen , A. Pfaltz and H. Yamamoto , Springer , Berlin , 1999 , vol. I–III
2. Asymmetric Catalysis on Industrial Scale: Challenges, Approaches, and Solutions , ed. H.-U. Blaser and H.-J. Federsel , Wiley-VCH , Weinheim , 2nd edn, 2010
3. Transition-Metal Catalysis of Nucleophilic Substitution Reactions: A Radical Alternative to SN1 and SN2 Processes
4. Transition metal–catalyzed alkyl-alkyl bond formation: Another dimension in cross-coupling chemistry
5. Engaging Radicals in Transition Metal-Catalyzed Cross-Coupling with Alkyl Electrophiles: Recent Advances
Cited by
10 articles.
订阅此论文施引文献
订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献