Five-co-ordinate complexes [MoH(SC6H2R3-2,4,6)3(PR′Ph2)](R = Me or Pri, R′= Me or Et) and their reactions with nitrogen donors. Crystal structures of [MoH(SC6H2Pri3-2,4,6)3(C5H5N)(PMe2Ph)], [MoH(NC5H4S-2)2(SC6H2Pri3-2,4,6)(PEtPh2)] and [PPh4][MoO(SC6H2Pri3-2,4,6)4]-Reference-Cited by-同舟云学术

Five-co-ordinate complexes [MoH(SC6H2R3-2,4,6)3(PR′Ph2)](R = Me or Pri, R′= Me or Et) and their reactions with nitrogen donors. Crystal structures of [MoH(SC6H2Pri3-2,4,6)3(C5H5N)(PMe2Ph)], [MoH(NC5H4S-2)2(SC6H2Pri3-2,4,6)(PEtPh2)] and [PPh4][MoO(SC6H2Pri3-2,4,6)4]

Published:1995 Issue:1 Volume: Page:5-15
ISSN:0300-9246
Container-title:J. Chem. Soc., Dalton Trans.
language:en
Short-container-title:J. Chem. Soc., Dalton Trans.

Author:

Hughes David L.,Lazarowych Natalie J.,Maguire Michael J.,Morris Robert H.,Richards Raymond L.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/1995/DT/DT9950000005

Reference35 articles.

1. R. L. Richards , in Biology and Biochemistry of Nitrogen Fixation, eds. M. J. Dilworth and A. R. Glenn, Elsevier, Oxford, 1991, p. 58;

2. Structural Models for the Metal Centers in the Nitrogenase Molybdenum-Iron Protein

3. Model hydrodesulfurization reactions: saturated tetrahydrothiophene and 1-butanethiol on molybdenum(110)

4. The preparation, structure, and reactions of the mononuclear thiolate–hydride complexes [MoH(SR)(dppe)2](R = bulky alkyl or aryl group, dppe = Ph2PCH2CH2PPh2); X-ray structure determination of cis-[MoH(SC6H2Pri3-2,4,6)(dppe)2]

5. Monohydride complexes of molybdenum(IV) and tungsten(IV) containing bulky thiolate ligands: X-ray crystal structures of [MH(SC6H2Pr I 3-2,4,6)3(PMe2Ph)2], M = Mo or W

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