Reactions of molybdenum and tungsten η2-C,C-vinyl complexes [Mη3-C(CF3)C(CF3)SR(CF3CCCF3)(η5-C5H5)] with alkynes leading to novel metallacycles
Author:
Publisher
Elsevier BV
Subject
Materials Chemistry,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Reference24 articles.
1. Cyclopentadienyl-ruthenium and -osmium chemistry
2. Synthetic, spectroscopic and structural studies of metallacyclopentadiene complexes of tungsten; the crystal structure of [(CF3)(SPri)-(4-MeC6H4NC)2(η5-C5H5)]
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1. WCl(η2-C2Ph2)(η6-C6Ph6H): A Compound Containing a Metallacycloheptatriene Unit from Trimerization of Diphenylacetylene with W(NMe3)(η2-C2Ph2)3;Organometallics;2002-06-01
2. Activation of Terminal Alkynes at the Sulfur-Rich Bimetallic Site [MoIII2Cp2(μ-SMe)3]+: Alkyne−Vinylidene Conversion and C−S and C−C Couplings Promoted by Addition of Unsaturated Substrates (RC⋮CH, RN⋮C, SCS). Crystal Structures of μ-η1:η2-Vinylidene, μ-η1:η2-Acetylide, and μ-η1:η3-Vinyl−Thioether Compounds;Organometallics;2001-02-22
3. Reactions of alkynes with molybdenum and tungsten bis(alkyne) complexes [M(SR)(CF3CCCF3)2(η5-C5H5)] (M = Mo, R = C6F5; M = W, R = C6H4Me-4): crystal and molecular structure of [Mo{η4-C(CF3)C(CF3)C(CO2Me)C(CO2Me)(SC6F5)}(CF3CCCF3)(η5-C5H5)] †;Journal of the Chemical Society, Dalton Transactions;1999
4. Reactions of Terminal and Bridging Thiol Di-μ-methylene Dirhodium Complexes with Alkynes to Afford the Corresponding Ethenethiolate Complexes. Remarkable C−C Bond Formation between Two μ-CH2 and Alkynes on the Bridging Ethenethiolate Complexes;Organometallics;1998-10-01
5. Synthesis, structure and reactivity of η4(5e)-butadienyl substituted molybdenum complexes;J. Chem. Soc., Dalton Trans.;1996
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