Reactions of Terminal and Bridging Thiol Di-μ-methylene Dirhodium Complexes with Alkynes to Afford the Corresponding Ethenethiolate Complexes. Remarkable C−C Bond Formation between Two μ-CH2 and Alkynes on the Bridging Ethenethiolate Complexes-Reference-Cited by-同舟云学术

Reactions of Terminal and Bridging Thiol Di-μ-methylene Dirhodium Complexes with Alkynes to Afford the Corresponding Ethenethiolate Complexes. Remarkable C−C Bond Formation between Two μ-CH2 and Alkynes on the Bridging Ethenethiolate Complexes

Published:1998-10-01 Issue:22 Volume:17 Page:4875-4883
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Kaneko Yuichi¹,Suzuki Nobuyuki¹,Nishiyama Aki¹,Suzuki Takayoshi²,Isobe Kiyoshi³

Affiliation:

1. Department of Chemistry, Faculty of Science, Kochi University, Akebono-cho, Kochi 780-8520, Japan

2. Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan

3. Department of Material Science, Graduate School of Science, Osaka City University, Sugimoto, Sumiyoshi-ku, Osaka 558-8585, Japan

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om980299i

Reference51 articles.

1. Metal perfluoro-alkane- and -arene-thiolates. Part IV. The reactions of some manganese, iron, and cobalt derivatives with alkynes

2. Organothiometallate addition reactions with electronegative alkynes. The X-ray molecular structures of [(η5-C5H5)(CO)FeC(O)C(CF3)CHSMe], [(η5-C5H5)(CO)FeC(CF3)CHS(Me)Fe(CO)(η5-C5H5)SMe], and [(η5-C5H5)(CO)MoC(O)C(CF3)C(CF3)C(O)SMe]

3. Reactions de quelques cyclopentadienyl methanethiolato fer et ruthenium avec des acetylenes fluores. Mise en evidence d'une double insertion d'un carbonyle et d'un acetylene

4. Reactions of some iron and tungsten mercapto-complexes with electrophilic acetylenes leading to novel metallacycles. The crystal and molecular structure of the η2-vinyl complex [W{η2-C(CF3)C(CF3)C(O)SMe}(CO)2(η5-C5H5)]

5. Metal-promoted insertion and cyclisation reactions of alkynes: the crystal and molecular structures of [Moη4- C(CF3)C(CF3)C(CF3)C(CF3)SPri (PEt3) (η5-C5H5)] and [Moη1-C(CF3)C(CF3)SC6F5 (CF3CCCF3)(O)(η5-C5H5)]

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