Synthesis of novel triosmium alkylidene carbonyl clusters. Crystal structures of [Os3(μ-H) 2(CO)9(μ3-CNC5H4-CHCH2)] and [Os3(μ-H)(CO)9(μ-C(H) NC5H4-η2-CHCH2)]
Author:
Publisher
Elsevier BV
Subject
Materials Chemistry,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Reference6 articles.
1. Some reactions of [Os3(µ-H)3(CO)9(µ3-CX)](X = OMe or Cl): the formation of C–N and C–P bonds
2. Indirect location of hydride ligands in metal cluster complexes
3. The Hydrido-Transition Metal Cluster Complexes
4. Structural studies on polynuclear osmium carbonyl hydrides. 2. Direct location of the .mu.2-hydride ligand and characterization of the 1,3-dipolar :C-HCH2P+Me2Ph ligand in the .mu.-hydrido-decacarbonyl(dimethylphenylphosphine)-.mu.-vinyl-triosmium molecule
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2. Reactions of triosmium and triruthenium clusters with 2-ethynylpyridine: new modes for alkyne C–C bond coupling and C–H bond activation;RSC Advances;2020
3. New molecular architectures containing low-valent cluster centres with di- and trimetalated 2-vinylpyrazine ligands: synthesis and molecular structures of Ru5(CO)15(μ5-C4H2N2CHCH)(μ-H)2 and Ru8(CO)24(μ7-C4H2N2CHC)(μ-H)3;RSC Advances;2019
4. Synthesis and characterization of a series of polymer-immobilized clusters of osmium;Journal of Organometallic Chemistry;2018-09
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