New molecular architectures containing low-valent cluster centres with di- and trimetalated 2-vinylpyrazine ligands: synthesis and molecular structures of Ru5(CO)15(μ5-C4H2N2CHCH)(μ-H)2 and Ru8(CO)24(μ7-C4H2N2CHC)(μ-H)3
Author:
Affiliation:
1. Department of Chemistry
2. Jahangirnagar University
3. Dhaka 1342
4. Bangladesh
5. University of North Texas
6. Denton
7. USA
8. King's College London
9. Britannia House
10. London SE1 1DB
11. UK
Abstract
Reaction of 2-vinylpyrazine with Ru3(CO)12 results in multiple C–H bond activations to afford Ru5 and Ru8 clusters.
Funder
Welch Foundation
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/RA/C9RA03841H
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4. Ortho-Selective Allylation of 2-Pyridylarenes with Allyl Acetates Catalyzed by Ruthenium Complexes
5. Intramolecular CH activation by dicationic Pt(II) complexes
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