Reactions of the unsaturated triosmium cluster [(μ-H)Os3(CO)8(Ph2PCH2P(Ph)C6H4)] with HX (X=Cl, Br, F, CF3CO2,CH3CO2): X-ray structures of [(μ-H)Os3(CO)7(η1-Cl)(μ-Cl)2(μ-dppm)],[(μ-H)2Os3(CO)8(Ph2PCH2P(Ph)C6H4)]+[CF3O]− and the two isomers of [(μ-H)Os3(CO)8(μ-Cl)(μ-dppm)]-Reference-Cited by-同舟云学术

Reactions of the unsaturated triosmium cluster [(μ-H)Os3(CO)8(Ph2PCH2P(Ph)C6H4)] with HX (X=Cl, Br, F, CF3CO2,CH3CO2): X-ray structures of [(μ-H)Os3(CO)7(η1-Cl)(μ-Cl)2(μ-dppm)],[(μ-H)2Os3(CO)8(Ph2PCH2P(Ph)C6H4)]+[CF3O]− and the two isomers of [(μ-H)Os3(CO)8(μ-Cl)(μ-dppm)]

Published:2005-06 Issue:12 Volume:690 Page:3044-3053
ISSN:0022-328X
Container-title:Journal of Organometallic Chemistry
language:en
Short-container-title:Journal of Organometallic Chemistry

Author:

Kabir Shariff E.,Miah Md. Arzu,Sarker Nitai C.,Hossain G.M. Golzar,Hardcastle Kenneth I.,Rokhsana Dalia,Rosenberg Edward

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference49 articles.

1. Internuclear exchange of carbonyl groups in Os3(CO)12: coupling constants J(187Os–13C) in trinuclear osmium carbonyls

2. Protonation of some polynuclear carbonyl complexes

3. Chemistry of polynuclear compounds. Part XXII. Protonation of triosmium dodecacarbonyl and some related compounds

4. Three isomeric hydride compounds formed by protonation of decacarbonyl-bis(dimethylphenylphosphine)triosmium and the X-ray structures of two of these: 1,1- and 1,2-[Os3H(CO)10(PMe2Ph)2][PF6]

5. Protonation and hydrogenation of triosmium clusters containing the bridging diphosphine ligands Ph2P(CH2nPPh2 (n  1 to 4)

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1. Thermolysis of Ru3(CO)8(µ-dppm)(µ-dpam): Transformation of bis(diphenylphosphino)methane and bis(diphenylarsino)methane;Polyhedron;2018-11

2. Reversible C-H bond activation at a triosmium centre: A comparative study of the reactivity of unsaturated triosmium clusters Os 3 (CO) 8 (μ-dppm)(μ-H) 2 and Os 3 (CO) 8 (μ-dppf)(μ-H) 2 with activated alkynes;Journal of Organometallic Chemistry;2017-05

3. A comparative study of the reactivity of the lightly stabilized cluster [Os3(CO)8{μ3-Ph2PCH2P(Ph)C6H4}(μ-H)] towards tri(2-thienyl)-, tri(2-furyl)- and triphenyl-phosphine;Journal of Organometallic Chemistry;2014-02

4. Backbone modified small bite-angle diphosphines: Synthesis, structure, and DFT evaluation of the thermal activation products based on Os3(CO)10{μ-Ph2PC(Me)2PPh2};Journal of Organometallic Chemistry;2014-01

5. Backbone Modified Small Bite-Angle Diphosphines: Synthesis, Structure and Regioselective Thermal Rearrangements of Os3(CO)10{μ-Ph2PCH(Me)PPh2};Journal of Cluster Science;2012-04-28