Reactions of the dirhenium(II) complexes Re2X4(μ-dppm)2 (X=Cl, Br; dppm=Ph2PCH2PPh2) with isocyanides. Part XVII. Isomerizations of triply bonded dirhenium complexes of the type [Re2X3(μ-dppm)2(CO)(CNXyl)(CNR)]+(R=Xyl or t-Bu) with open bioctahedral structures to di-μ-chloro edge-sharing bioctahedral structures with no Re

Reactions of the dirhenium(II) complexes Re2X4(μ-dppm)2 (X=Cl, Br; dppm=Ph2PCH2PPh2) with isocyanides. Part XVII. Isomerizations of triply bonded dirhenium complexes of the type [Re2X3(μ-dppm)2(CO)(CNXyl)(CNR)]+(R=Xyl or t-Bu) with open bioctahedral structures to di-μ-chloro edge-sharing bioctahedral structures with no Re–Re bond

Published:1999-01 Issue:1-2 Volume:573 Page:87-95
ISSN:0022-328X
Container-title:Journal of Organometallic Chemistry
language:en
Short-container-title:Journal of Organometallic Chemistry

Author:

Ding Yan,Kort David A.,Wu Wengan,Fanwick Phillip E.,Walton Richard A.

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference35 articles.

1. Part XVI. W. Wu, P.E. Fanwick, R.A. Walton, Inorg. Chem. 37 (1998) 3122.

2. Multiple Bonds Between Metal Atoms;Cotton,1993

3. Mononuclear and Polynuclear Chemistry of Rhenium (III): Its Pronounced Homophilicity

4. Compounds Containing Dirheniurm(III) Octahalide Anions

5. See chapter 5 of Ref. [2] for a recent review of this chemistry.

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1. Mixed-Metal Assemblies Containing Multiply Bonded Dirhenium Species Linked through Thiocyanate- and Cyanide-Containing Bridging Units;Inorganic Chemistry;2001-09-18

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4. Reactions of the Dirhenium(II) Complexes Re2X4(μ-dppm)2 (X = Cl, Br; dppm = Ph2PCH2PPh2) with Isocyanides. 21.1 A Comparison with the Complexes Re2Cl4(μ-dppE)2 and Re2Cl4(μ-dcpm)2 (dppE = Ph2PC(CH2)PPh2; dcpm = Cy2PCH2PCy2) and the Structural Characterization of Complexes of the Types Re2Cl4(μ-LL)2(CNR), Re2Cl4(μ-LL)2(CNR)2, and [Re2Cl3(μ-LL)2(CNR)3]+ (LL = dppm, dppE, dcpm; R = t-Bu, Xyl);Inorganic Chemistry;2000-05-19

5. Dirhenium complexes that contain the ligand 1,1-bis(diphenylphosphino)ethene (dppE). Synthesis, characterization and reactivity of Re2Cl4(μ-dppE)2;Inorganica Chimica Acta;2000-04