Mixed-Metal Assemblies Containing Multiply Bonded Dirhenium Species Linked through Thiocyanate- and Cyanide-Containing Bridging Units
Author:
Affiliation:
1. Department of Chemistry, Purdue University, 1393 Brown Building,West Lafayette, Indiana 47907-1393
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic010442r
Reference33 articles.
1. Reactions of the dicarbonyl complex Re2Cl4(dppm)2(CO)2 with nitriles and isocyanides. Synthesis of [Re2Cl3(dppm)2(CO)2L]n+ (n = 0, 1; L = RCN, RNC) and the structural characterization of [Re2Cl3(dppm)2(CO)2(NCC2H5)]PF6
2. Reactions of the dirhenium(II) complexes Re2X4(dppm)2 (X = Cl or Br; dppm = Ph2PCH2PPh2) with isocyanides. 4. Isomerism in mixed carbonyl-isocyanide complexes of stoichiometry [Re2Cl3(dppm)2(CO)2(CNR)]n+ (n = 0 or 1) and [Re2Cl3(dppm)2(CO)(CNR)2]+ (R = tert-Bu or xylyl), which possess edge-shared bioctahedral structures
3. Carbonylation of the triply bonded dirhenium(II) complexes Re2X4(dppm)2 (X = chloro, bromo; dppm = bis(diphenylphosphino)methane) to give [Re2X3(dppm)2(CO)3]PF6 and [Re2X3(dppm)2(CO)2]PF6. Structural characterization of [(CO)ClRe(.mu.-Cl)(.mu.-CO)(.mu.-dppm)2ReCl(CO)]PF6
4. Reactions of the dirhenium(II) complexes Re2X4(dppm)2 (X = Cl, Br; dppm = Ph2PCH2PPh2) with isocyanides. 5. Mixed carbonyl-isocyanide and carbonyl-isocyanide-nitrile compleses of stoichiometry [Re2Cl3(dppm)2(CO)(CNR)(L)]PF6(R = t-Bu, xyl (xylyl); L = t-BuNC, xylNC, MeCN, EtCN). Structural characterization of the ca
5. Reactions of the dirhenium(II) complexes Re2X4(dppm)2 (X = Cl, Br; dppm = Ph2PCH2PPh2) with isocyanides VI. Further studies on isomers of the edge-sharing bioctahedral species [Re2C13(μ-dppm)2(CO)(CNxyl)2]+
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