Abstract
A study has been made of
the applicability of a linear free energy relationship describing the effect of
pressure on the equilibrium and rate constants of chemical reactions. Some
properties of the relationship have been analysed and corollaries, including
linear dependences, obtained which make it possible to calculate reaction
enthalpies and entropies, volume changes and Hammett's p-constants at high
pressures. Ionization reactions have been used as examples to illustrate the
conclusions arrived at. The linear free energy relationship has been shown to
describe the effect of pressure up to 8000 bars on the ionization constants of
acids and on the pH of buffer solutions.
Cited by
21 articles.
订阅此论文施引文献
订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献