An electrochemical investigation of azole derivative on aluminum in 0.25 M HCl solution using EN and EIS techniques

Abstract

Purpose This study attempts to investigate corrosion inhibition properties of 1H-benzimidazole (B) and 1H-benzotriazole (BTA) on aluminum in 0.25 M HCl solution at different concentrations. Design/methodology/approach To this end, electrochemical techniques including electrochemical noise (EN), electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization were used. Findings Results showed a greater corrosion inhibition efficiency of BTA than B on aluminum in HCl solution. BTA showed greater tendency to adsorption on the metal surface than B because of the inclusion of three nitrogen atoms. Originality/value The novelty of this work is comparing EN data with EIS and potentiodynamic polarization parameters.