Corrosion inhibition of aluminium in hydrochloric acid medium using cimetidine as inhibitor: empirical and optimization studies

Abstract

Purpose The purpose of this study was to investigate cimetidine as corrosion inhibitor of aluminium in hydrochloric acid medium. Design/methodology/approach Cimetidine was characterized by gas chromatography mass spectrophotometer and Fourier transform infrared spectroscopy to determine its chemical composition and functional groups, respectively. Gravimetric, potentiodynamic polarization and electrochemical impedance spectroscopic techniques were used in the corrosion inhibition process. Thermodynamic and adsorption parameters were evaluated. And response surface methodology was used to optimize the corrosion inhibition process. Findings Analysis of the results revealed that major constituents of cimetidine include metronidazole, n-hexadecanoic acid cyclohexane and methyl ester. It has C-H stretch, C = N stretch, CH3C-H bend, ring C = C stretch, -C-O-O stretch, N-H bend, C-O stretch and C-H bend as predominant functional groups. Adsorption of molecules of the inhibitor on the aluminium surface was spontaneous, and it followed mechanism of physical adsorption. Response surface methodology revealed that quadratic model adequately described the inhibition efficiency of cimetidine as function of inhibitor concentration, temperature and time. Chemical and electrochemical results are in agreement that the cimetidine is a viable corrosion inhibitor. Cimetidine was revealed as mixed-type inhibitor because it controlled both cathodic and anodic reactions. Originality/value Empirical and optimization studies of cimetidine drug as corrosion inhibitor of aluminium in hydrochloric acid medium were carried out. The research results can provide the basis for deploying drugs (with mucosal protective and antacid properties) for corrosion control of metallic structures.