Corrosion inhibition of aluminium in 0.3 M HCl using starch mucor in potassium iodide as inhibitor

Author:

Ezeamaku Uchenna Luvia,Eze Innocent,Odimegwu Nkiru,Nwakaudu Angela,Okafor Amarachukwu,Onukwuli Okechukwu Dominic,Nnanwube Ikechukwu Abuchi

Abstract

Purpose The purpose of this study is to investigate starch mucor (SM) in potassium iodide (KI) as corrosion inhibitor of aluminium in hydrochloric acid (HCl) medium. Design/methodology/approach The SM in KI was characterized by gravimetric, scanning electron microscopy, electrochemical impedance spectroscopy measurements, potentiodynamic polarization and gas chromatography-mass spectrometer techniques. The inhibition efficiency was optimized using response surface methodology. Findings The result revealed that the inhibitor inhibited corrosion at a low concentration with the rate of inhibition increasing as the concentration of the inhibitor increased. The inhibition efficiency increases as the temperature was increased with slight incorporation of the inhibitor (SM in KI). This indicates that the corrosion control is both inhibitor (SM in KI) and temperature dependent. Originality/value The research results can provide the basis for using SM in KI as corrosion inhibitor of aluminium in HCL medium. Mixed-type inhibitor nature of SM was proved by cathodic and anodic nature of the polarization curves.

Publisher

Emerald

Subject

Materials Chemistry,Surfaces, Coatings and Films

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