Molecular interaction studies on the binding ability of hydrated zinc sulphate with aqueous solution of ascorbic acid at different temperatures

Abstract

Abstract The ternary systems containing Water, Ascorbic acid (AA) and ZnSO4·7H2O were investigated using three approaches namely volumetric studies, viscosity studies and conductance studies. The solvent systems used were 2, 4 and 6% (by weight) of AA in water. The studies were conducted at four temperatures (303.15–318.15 K with an interval of 5 K) and pressure 0.1 MPa with concentration of ZnSO4·7H2O in the solution ranging from 0.01 to 0.12 m. Various parameters like partial molar volume (ϕ v), apparent molar volume ( ϕ v o ) $({\phi }_{\text{v}}^{\text{o}})$ , Hepler’s constant ( ( d 2 ϕ v o / d T 2 ) p ) $({({d}^{2}{\phi }_{\text{v}}^{\text{o}}/d{T}^{2})}_{p})$ , partial molar expansibility ( ϕ E o ) $({\phi }_{\text{E}}^{\text{o}})$ and transfer volume ( Δ t r ϕ v o ) $({{\Delta}}_{tr}{\phi }_{\text{v}}^{\text{o}})$ have been evaluated from volumetric studies. The viscosity studies have yielded Jones-Dole parameters (A and B) and free energy of activation per mole for solvent ( Δ μ 1 0 ‡ ) $({\Delta}{\mu }_{1}^{0{\ddagger}})$ and solute ( Δ μ 2 0 ‡ ) $({\Delta}{\mu }_{2}^{0{\ddagger}})$ . The conductance data has been used to calculate molar conductance (Λm), limiting molar conductance ( Λ m o ) $({{\Lambda}}_{\text{m}}^{\text{o}})$ and Walden product ( Λ m o η o ) $({{\Lambda}}_{\text{m}}^{\text{o}}{\eta }_{\text{o}})$ . The results of these studies agree with each other and have concluded the structure breaker behavior of ZnSO4·7H2O in the solvent system containing AA and water.