Effective properties of heterogeneous materials as functions of contrast between properties of constituents

Abstract

One of the key difficulties in applications of the effective media theories to real materials is the complex and “irregular” character of microstructures. However, in cases of moderate contrast between properties of the constituents, the sensitivity of the effective properties to microgeometries is much lower; it vanishes in the first approximation. The latter actually remains applicable at substantial (up to 70%–100%) contrast in properties. The effective elastic and conductive properties are considered as functions of property contrast between constituents. Whereas in the isotropic cases the Voigt–Reuss bounds provide guidance, in anisotropic cases these issues are less obvious. Two origins of effective anisotropies are discussed: (A) anisotropy of material constants and (B) geometric factors: non-random orientations of non-spherical inclusions. To the first order in contrast, the factor (A) is dominant, and factor (B) can be ignored (effective properties are independent of microgeometries, such as inhomogeneity shapes); the importance of factor (B) increases sharply with increasing contrast. For matrix composites (continuous matrices containing inhomogeneities), an interesting interplay takes place between the moderate contrast assumption and the non-interaction assumption (NIA). It shows that, in cases of moderate contrast, the NIA remains accurate at substantial concentrations. An application to monitoring fatigue of austenitic steel, whereby property contrast between the martensite and austenite phases is moderate, is discussed. Results of the second order in contrast, that are limited to the ellipsoidal inhomogeneities, are also given.