Affiliation:
1. School of Material Science and Engineering, Jiangsu University, Zhenjiang, People’s Republic of China
2. Zhejiang Economics and Trade Polytechnic, Hangzhou, People’s Republic of China
Abstract
In this article, polyimide (PI) composite films reinforced by graphitic carbon nitride (g-C3N4) have been synthesized using the in situ polymerization process via thermal imidization. Poly (amic acid) (PAA) solutions were prepared from pyromellitic dianhydride (PMDA) and 4,4′-(4,4′-isopropylidenediphenyl-1,1′-diyldioxy) dianiline (BAPP) in N,N-dimethylacetamide (DMAc) solvent. The different amounts of g-C3N4 obtained from the direct pyrolysis of dicyandiamide (DCDA) at 600°C were incorporated into PAA matrix, which formed g-C3N4/PI composite films by thermal imidization. The morphological structures of the synthesized g-C3N4 and g-C3N4/PI composite films were characterized using fourier transform infrared spectroscopy, x-ray diffraction, scanning electron microscopy and transmission electron microscopy. With 2 wt% g-C3N4 incorporated, the tensile strength and elongation at break of g-C3N4/PI composites were increased by about 23% and 21%, respectively, due to the strong interaction between the g-C3N4 particles and PI. Thermogravimetric analysis indicated that the incorporation of g-C3N4 improved the thermal stability of the PI at low g-C3N4 content. Besides, the dielectric and optical properties of these composites were also studied in this article.
Subject
Materials Chemistry,Organic Chemistry,Polymers and Plastics
Cited by
19 articles.
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