PEEK composites with polyimide sizing SCF as reinforcement: Preparation, characterization, and mechanical properties

Abstract

In this work, the surface modification of short carbon fibers (SCFs) using polyimide (PI) as a sizing agent was conducted and fully characterized, and SCF-reinforced polyether ether ketone (PEEK) composites were obtained by extrusion and injection molding. The surface characteristics of the PI-coated SCFs were evaluated using scanning electron microscopy and X-ray photoelectron spectroscopy. The results indicated that a uniform PI sizing layer was formed on the surfaces of the SCFs. Thermogravimetric analysis results demonstrated that PI-coated SCFs had better thermal stability than commercial SCFs. The tensile strength and flexural strength of the PI-coated SCF/PEEK composites showed improvements of 11.8% and 16.6% compared with the commercial cases, which were attributed to the PI sizing treatment effectively improving the interfacial adhesion between the SCF and the PEEK matrix. Dynamic mechanical analysis and the morphologies of tensile fracture surfaces suggested better interfacial adhesion between the fibers and the PEEK matrix, which were in good agreement with the mechanical properties. Due to the convenient processing of PI sizing as well as the effectively improved mechanical properties of the composites, the PI-sizing methodology has great potential application in the field of fiber-reinforced high-temperature engineering plastics composites.