New trends in cellular silicone: Innovations and applications

Abstract

The purpose of this article is to provide an overview of manufacturing processes used in the development of cellular silicone for a wide variety of applications. The combination of intrinsic properties of silicone and foam is considered as an attractive solution in many applications. With regard to the long-standing interest of the industry in silicone chemistry, foaming is very common from hydrosilylation/condensation reactions. This well-known technology leads to homogeneous, elastic, low density and biocompatible foams. However, the size of the cells remains large, the reactions are sensitive to humidity and the dangerousness of the hydrogen could be an industrial concern. Many researches are moving towards alternatives to the manufacture of silicone cellular materials such as gas foaming, phase separation, emulsion and sacrificial models, and syntactic charges. In addition, the theories of sorption, diffusion, nucleation and cell growth are detailed to explain the formation of gaseous foam. CO2 is commonly used to physically foam silicone because of its good solubility. However, the diffusive behavior of CO2 is high in silicone as explained by the free volume theory. Silicone–CO2 foaming is essentially triggered by rapid depressurization leading to a cell density around 1 × 109 cells/cm3 in the best case. In addition, templated foams are divided into emulsion polymerization (polyHIPE), sacrificial foams and syntactic foams. These methods are simple because they do not need specific foaming equipments. Pore sizes are also tunable as function of template sizes.