Fabrication of CoFe‐layered double hydroxide for flame retardant and smoke suppression of silicone rubber foam

Abstract

AbstractIn order to improve the flame retardancy and smoke suppression of silicone rubber foam (SRF), the CoFe‐LDH was fabricated by coprecipitation method and used as flame‐retardant ingredient in SRF. The influence of CoFe‐LDH on the flame retardancy, combustion behavior, and thermal stability of SRF was investigated. The results demonstrate that SRF containing only 1.0 phr CoFe‐LDH can pass V‐0 rating in the vertical combustion test, with a limiting oxygen index of 28.6%. The total heat release and total smoke production are 22.2% and 61.1% lower than that of SRF, respectively. Moreover, CoFe‐LDH can improve the thermal stability of SRF in the high temperature range, and the char residue at 900°C of SRF/LDH composite is obviously higher than that of pure SRF. In addition, to further understand the flame‐retardant mechanism of CoFe‐LDH, the micromorphology of the char residue and the gaseous products during heating for SRF and SRF/LDH composite were analyzed. The results indicate that CoFe‐LDH exhibits excellent flame‐retardant effects in both condensed and gaseous phases for its functions of catalysis, carbonization, and nonflammable gas release. This study provides a more efficient and convenient strategy for the flame retardant and smoke suppression research of SRF.