Production and mechanical characterization of LLDPE biocomposite filled with almond shell powder

Abstract

Substitution of synthetic polymers by polymers prepared from renewable resources as well as synthetic fibers by natural fibers is a current research topic. They target various sectors of application such as the automotive industry, transport, packaging, building, and so on, that can offer a solution of lightness, great performance, and a minimum impact on the environment. In the present study, biocomposites based on linear low-density polyethylene (LLDPE) reinforced with nonchemically treated and noncompatibilized almond shell powder (ASP) particles were prepared by an elaboration process based on mixing polymer powder with ASP particles having similar density in solid state. For consolidation, thermocompression technique has been used. The mass ratio of ASP in the LLDPE/ASP composites varied from 10 wt% to 40 wt%. Effects of ASP wt% on the mechanical and structural properties of biocomposites have been explored through tensile and shore D hardness tests as well as microscopic observations. Homogenous repartition of ASP particles in the polymer matrix was observed for less than 20 wt% ASP. For more than 20 wt% ASP, agglomeration of fillers particles has been observed. Also, it has been found that elastic modulus of the biocomposites increases with ASP particles wt%, while tensile strength and ductility decrease when the ASP wt% increases.