Employing Na₂CO₃ and NaCl as sources of sodium in NaFePO₄ cathode: A comparative study on structure and electrochemical properties

Abstract

<abstract> <p>Encouraged by the tremendous success of lithium iron phosphate (LiFePO₄), analogous NaFePO₄ has been predicted to show identical properties as LiFePO₄. Synthesis of NaFePO₄ materials in the maricite phase has been carried out using the sol-gel method with variations of calcination temperature and starting materials as sources of sodium Na₂CO₃ and NaCl. The resulted NaFePO₄ maricite phase with the purity between 40% and 85%, according to X-ray diffractometry (XRD) characterization was obtained. The morphology and grain size of the particles in samples, as observed by a scanning electron microscope (SEM), tend to enlarge upon calcination at higher temperatures. The increment of calcination temperature increases the NaFePO₄ maricite phase content in the sample. The impedance data analysis shows that the diffusion coefficient of Na⁺ ions and the electrical conductivity of a sample using Na₂CO₃ is higher than that of NaCl. This comprehensive study provides a feasible method and opens new opportunities for the continuous study of Na-ion batteries.</p> </abstract>