Photophysical and ligand binding studies of metalloporphyrins bearing hydrophilic distal superstructure

Abstract

UV-vis absorption and emission studies on zinc and iron porphyrin complexes bearing H-bonding distal superstructures have been performed in two different organic solvents- tetrahydrofuran (THF) (coordinating) and dichloromethane (DCM) (non-coordinating). Quantum yields and lifetimes have been measured for these complexes which are in good agreement with the other reported metalloporphyrins. Binding affinities with anionic ligands such as N3- , CN- , S-2 , F- were monitored for these two complexes in aqueous media and the respective binding constant values were calculated. The Zn complex shows more selectivity towards cyanide while the Fe complex shows more selectivity towards azide.