A study of the effect of axial ligand steric hindrance-Reference-Cited by-同舟云学术

A study of the effect of axial ligand steric hindrance

Published:2018-07 Issue:07 Volume:22 Page:588-595
ISSN:1088-4246
Container-title:Journal of Porphyrins and Phthalocyanines
language:en
Short-container-title:J. Porphyrins Phthalocyanines

Author:

Hu Chuanjiang¹,Oliver Allen G.²,Turowska-Tyrk Ilona²³,Scheidt W. Robert²

Affiliation:

1. State and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, Jiangsu, China

2. Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, Indiana 46556, USA

3. Present address: Faculty of Chemistry, Wrocław University of Science and Technology, Wybrzeże Wyspiańskiego 27, 50–370 Wrocław, Poland

Abstract

The molecular structures of three porphyrinate derivatives have been determined by X-ray studies. Two derivatives, [Fe(TTP)(1-MeIm)[Formula: see text]] · 2C[Formula: see text]H[Formula: see text] and [Fe(T-[Formula: see text]-OCH[Formula: see text]PP)(BzHIm)[Formula: see text]] are iron(II) derivatives, whereas the third, [Fe(TMP)(BzHIm)[Formula: see text]]ClO[Formula: see text] · 2CHCl[Formula: see text], is an iron(III) species. The structure determinations provide evidence of the importance of steric effects, either from the axial ligand or the porphyrin ligand, in defining the overall stereochemistry.

Publisher

World Scientific Pub Co Pte Lt

Subject

General Chemistry

Link

https://www.worldscientific.com/doi/pdf/10.1142/S1088424618500700

Reference35 articles.

1. Syntheses of ferrous-porphyrin complexes. Hypothetical model for deoxymyoglobin

2. Structure of the Deoxymyoglobin Model [Fe(TPP)(2-MeHIm)] Reveals Unusual Porphyrin Core Distortions

3. Electronic Configuration Assignment and the Importance of Low-Lying Excited States in High-Spin Imidazole-Ligated Iron(II) Porphyrinates

4. Electronic Configuration of High-Spin Imidazole-Ligated Iron(II) Octaethylporphyrinates

5. Hydrogen Bonding Effects on the Electronic Configuration of Five-Coordinate High-Spin Iron(II) Porphyrinates

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